TRICHY CHEMICAL ENGGSEM SYLLABUS

ANNA UNIVERSITY TIRUCHIRAPPALLI Tiruchirappalli - 620 024
Regulations 2007 Curriculum
B.TECH. CHEMICAL ENGINEERING
SEMESTER V
S.No. Subject Code Subject L T P Max. Marks
Theory
1 Statistics and Linear Programming 3 1 0 100
2 Fluid Mechanics 3 1 0 100
3 Mechanical Operations 3 1 0 100
4 Chemical Thermodynamics Principles 3 1 0 100
5 Organic Chemical Technology 4 0 0 100
6 Instrumental Methods of Analysis 3 1 0 100
Practical
7 Fluid Mechanics Laboratory 0 0 3 100
8 Mechanical Operations Laboratory 0 0 3 100
9 Communication and Soft Skills Laboratory 0 0 3 100
ANNA UNIVERSITY TIRUCHIRAPPALLI
Tiruchirappalli - 620 024
LT P
3 10
Regulations 2007
Syllabus
B.TECH. CHEMICAL ENGINEERING SEMESTER V
STATISTICS AND LINEAR PROGRAMMING
UNIT I PROBABILITY AND RANDOM VARIABLE 9
Axioms of probability - Conditional probability - Total probability - Bayes theorem - Random variable - Probability mass function - Probability density function - Properties- Moments - Moment generating functions and their properties.
UNIT II STANDARD DISTRIBUTIONS 9
Binomial- Poisson- Geometric- Negative Binomial- Uniform- Exponential- Gamma- Weibull and Normal distributions and their properties - Functions of a random variable.
UNIT III TESTING OF HYPOTHESIS 9
Sampling distributions - Testing of hypothesis for mean, variance, proportions and differences using Normal, t, Chi-square and F distributions - Tests for Independence of attributes and Goodness of fit.
UNIT IV LINEAR PROGRAMMING 9
Formulation of linear programming problem - Graphical solution - Simplex algorithm - Artificial variable - Big M method - Two phase method.
UNIT V FURTHER TOPICS IN LINEAR PROGRAMMING 9
Duality - Primal, Dual computations - Dual simplex algorithm - Transportation and Assignment models.
L: 45 T: 15 Total: 60
TEXT BOOKS
1. Johnson, R. A., "Miller & Freund's Probability and Statistics for Engineers", Sixth Edition, Pearson Education, Delhi, 2000. (Chapters 3, 4, 5, 7, 8 & 9).
2. Taha, H. A., "Operations Research - An Introduction", Seventh Edition, Pearson Education Edition Asia, New Delhi, 2002.
REFERENCES
1. Walpole, R. E., Myers, R, H., Myers, S. L. and Ye. K, "Probability and Statistics for Engineers and Scientists", Seventh Edition, Pearson Education, Delhi, 2002.
2. Gupta, S.C, and Kapur, J.N., "Fundamentals of Mathematical Statistics", S. Chand and Co. Ninth Edition, New Delhi, 1996
3. Manmohan, P.K. and Gupta, S.C. "Operations Research", Sultan Chand & Co. Ninth Edition,
Delhi, 2001.
FLUID MECHANICS
LT P 3 10
UNIT I INTRODUCTION 9
The concept of fluid- The fluid as a continum - Laws of dimensional homogeneity - Properties of velocity field - Thermodynamic properties of a fluid - Viscosity and other secondary properties - Basic flow analysis techniques - Flow patterns.
UNIT II PRESSURE DISTRIBUTION IN A FLUID 9
Pressure and pressure gradient - Equilibrium of fluid element - Hydrostatic pressure distributions -Applications to manometry - Hydrostatic forces on planed and curved submerged surfaces - Laws of buoyancy and stability considerations for bodies in floatation.
UNIT III DIMENSIONAL ANALYSIS AND SIMILITUDE 9
The principle of dimensional homogeneity - The Pi-theorem - Non-dimensional action of the basic equations - Similitude - Relationship between dimensional analysis and similitude - Use of dimensional analysis for scale up studies.
UNIT IV VISCOUS FLOW IN DUCTS AND BOUNDARY LAYER FLOW 9
Reynold's number regimes- Internal versus external viscous flow- Flow in circular pipe - Head loss-Minor losses in pipe systems and multiple-pipe systems - Boundary layer concepts-Functions and pressure drag - Flow through fixed and fluidized beds.
UNIT V FLOW MEASUREMENT AND TUBRO MACHINERY 9
Constant and variable head meters - Working and applications of pumps and compressors - Working and applications of Needle / Check / Globe / Gate / Bell / Butterfly Valves.
L: 45 T: 15 Total: 60
TEXT BOOKS
1. Noel de Nevers, "Fluid Mechanics for Chemical Engineers", Second Edition, McGraw-Hill, 1991.
2. McCabe, W.L, Smith J.C and Harriot .P., "Unit Operations in Chemical Engineering", McGraw-
Hill, Sixth Edition 2000.
REFERENCES
1. Coulson J.M., and Richardson J.F., "Coulson and Richardson's Chemical Engineering", Vol-I, Third Edition, Butterworth - Heinemann Publishers, 2004.White, F.M., "Fluid Mechanics", 4th
Edition, McGraw-Hill Inc., 1999.
2. Daughenty, R.L., Franzini, J.B and Finnemore, E.J., "Fluid Mechanics with Engineering Applications", SI metric Edn., McGraw-Hill Book Company, 1989.
3. Darby, R. Chemical Engineering Fluid Mechanics, Marcel Dokker, 1998.
MECHANICAL OPERATIONS
LT P 3 1 0
UNIT I PARTICLE CHARACTERISTICS AND SIZE ANALYSIS 9
General characteristics of solids-Their behaviour under different external forces- Agglomeration-Techniques for size analysis- Storage and Conveying of solids.
UNIT II SIZE REDUCTION 9
Laws of size reduction- Classification of equipment- Methods of size reduction- Disintegration-Preparation of colloids.
UNIT III MECHANICAL SEPARATIONS 9
Screening and Screening equipment- Effectiveness of screens- Gravity settling- Sedimentation-Thickening- Centrifugal separation- Impingement methods- Industrial dust removing equipment with special reference to electrostatic and magnetic separators-Heavy media separations- Floatation.
UNIT IV FILTRATION 9
Theory of filtration- Batch and continuous filters- Centrifuges-Membrane and ultra filtration.
UNIT V MIXING AND AGITATION 9
Equipment for blending and kneading-Dispersion-Power for agitation-Correlations.
L: 45 T: 15 Total: 60
TEXT BOOKS
1. McCabe, W.L, Smith J.C and Harriot, P., "Unit Operations in Chemical Engineering", McGraw-Hill, Fourth Edition, 1984.
2. Coulson, J.M., Richardson, J.F., "Chemical Engineering", Volume 2, Third Edition, Pergamon Press, 1977.
REFERENCES
1. Badger W.L., and Banchero J.T., "Introduction to Chemical Engineering", Tata McGraw Hill, 1997
2. Richardson J.F. and Harker J.H., "Coulson and Richardson's Chemical Engineering", Vol-II Fourth Edition, Butterworth Heineman, 2004.
3. Bhattacharaya., "Mechanial Operations", Khanna publishers, 2001
CHEMICAL THERMODYNAMICS PRINCIPLES
LT P 3 10
UNIT I BASIC CONCEPTS 9
The terminologies of thermodynamics- The variables and quantities of thermodynamics-Categorization of systems and processes- Energy classifications- point and path properties- Energy in transition-Heat and work- Reversible and irreversible processes- Phase rule.
UNIT II FIRST LAW OF THERMODYNAMICS 9
The first law and internal energy- Statements of first law for the non flow and flow systems- Enthalpy and heat capacity - Limitations of the first law.
UNIT III SECOND LAW OF THERMODYNAMICS 9
Statements of the second law of thermodynamics- Available and unavailable energies- The entropy function-Applications of the second law.
UNIT IV THERMODYNAMIC FORMULATIONS 9
Measurable quantities-Basic energy relations- Maxwell relations- Thermodynamic formulations to calculate enthalpy- Internal energy and entropy as function of pressure and temperature-Other formulations involving Cp and Cv- Complex thermodynamic formulations- Thermodynamic properties of an ideal gas- Entropy change in reversible and irreversible process.
UNIT V THERMODYNAMIC PROPERTIES OF REAL GASES & COMPRESSION OF FLUIDS 9
The PVT behavior of fluids- Laws of corresponding states and equation of states approaches to the PVT relationships of non ideal gas Problems- Compressibility factors-Generalized equations of state-Property estimation via generalized equation of state- fugacity and fugacity coefficients of real gases-Thermodynamic aspects of compression process- Classification of compression processes-Basic equation for change of state of gases- The work expression for different situations- The effect of clearance volume- Multistage compression- Convergent divergent flow-Ejectors.
L: 45 T: 15 Total: 60
TEXT BOOKS
1. Smith, J.M., and Van Ness, H.C., "Introduction to Chemical Engineering Thermodynamics", Kogakushai 1976.
2. Narayanan K.V "A Text Book of Chemical Engineering Thermodynamics" Prentice Hall of India Pvt. Ltd. 2001.
REFERENCES
1. Dodge, B.F., "Chemical Engineering Thermodynamics", McGraw-Hill, 1960.
2. Sandler, S.I., "Chemical and Engineering Thermodynamics 2nd edn.", Wiley, 1989.
3. Kyle, B.G., "Chemical and Process Thermodynamics 2nd edn.", Prentice Hall of India Pvt. Ltd.,
1990.
ORGANIC CHEMICAL TECHNOLOGY
LT P 4 0 0
UNIT I SUGAR AND STARCH INDUSTRIES 12
Raw and refined sugar- By products of sugar industries-Starch and starch derivatives.
UNIT II OILS, FATS, SOAPS AND DETERGENT INDUSTRIES 12
Vegetable oils and animal fats-Their nature- Analysis and extraction methods-Hydrogenation of oils-Fatty acids and alcohols- Waxes- Soaps- Synthetic detergents.
UNIT III PETROLEUM AND PETROCHEMICAL INDUSTRIES 12
Petroleum refining- Physical and chemical conversion products- Lubricating oils- Petrochemical precursors- Methane- Olefins- Acetylenes and aromatics and products obtained from them by various unit processes.
UNIT IV RUBBER AND POLYMERS 12
Monomers - Thermosetting and Thermoplastic materials - General properties and Applications of Resins - Polymerization processes - Different types - Natural rubber; Synthetic rubber such as SBR-NBR- CR - Fundamental methods of processing of synthetic Rubbers.
UNIT V SYNTHETIC FIBRE AND FILM INDUSTRIES 12
Natural and synthetic fibers - Properties of - Poly amides - Manufacture of Nylon 6. 6. Polyesters Fibers - Manufacturer of - Cellulose Fibers - Viscose Rayon production manufacture of films -Cellulose Acetate-PVC- Polyesters - Polyethylene.
L: 60 Total: 60
TEXT BOOKS
1. Austin, G.T., "Shreve's Chemical Process Industries", Fifth Edition, McGraw-Hill International Book Co, Singapore, 1984.
2. Dryden, C.E., "Outlines of Chemical Technology", Edited and Revised by Gopala Rao. M. and M.Sittig, Second edition, Affiliated East-West press, 1993.
REFERENCES
1. Kent, J.A.(ed), "Riggel's Hand Book of Industrial Chemistry", Van Nostrant Reinhold, 1974.
2. CHEMTECH 1-4, "Chemical Engineering Education Development Centre", I.I.T., Madras 1975-78.
INSTRUMENTAL METHODS OF ANALYSIS
LT P
3 10
UNIT I INTRODUCTION TO SPECTROSCOPICAL METHODS OF ANALYSIS 9
ELECTROMAGNETIC RADIATION: Various ranges- Dual properties- Various energy levels-Interaction of photons with matter, absorbance, transmittance and their relationship- Permitted energy levels for the electrons of an atom and simple molecules- Classification of instrumental methods based on physical properties.
QUANTITATIVE SPECTROSCOPY: Beer-Lambert's Law- Limitations- Deviations (Real, Chemical Instrumental) Necesslerimetry - Duboscq colorimetry- Estimation of inorganic ions such as Fe, Ni and estimation of Nitrite using Deer-Lambert's Law.
UNIT II MOLECULAR SPECTROSCOPY 9
Various electronic transitions in organic and inorganic compounds effected by UV- Visible and infra red radiations-Various energy level diagrams of saturated- Unsaturated and carbonyl compounds-Excitation by UV and Visible radiations- Woodward-Fischer rules for the calculation of absorption maxima (dienes and carbonyl compounds)-Effects of auxochromes and effects of conjugation on the absorption maxima- Instrumentation for UV, VISIBLE and IR spectroscopies (source, Optical parts and Detectors)- Multicomponent analysis- Photometric titration (Experimental set-up and various types of titrations)- Applications of UV, VISIBLE AND IR spectrscopies.
UNIT III ATOMIC SPECTROSCOPY 9
Atomic Absorption Spectrophotometry: Principle- Instrumentation and Application- Various interferences observed in AAS (Chemical radiation and excitation)- Polarimetry and refractrometry-Principle,Instrumentation and Applications
UNIT IV ELECTROMETRIC METHODS OF ANALYSIS 9
Introduction of electrometric methods- Difference between redox and acid- Base reactions- Types of cells- Schematic representation of cell- Single electrode potential- Laboratory reference electrodes (Standard hydrogen- saturated calomel, Ag - AgCl and inert electrodes)- Ion-selective electrodes.
Potentiometry: Nernst equation- Experimental set-up and measurement of pH; Conductometry-Measurement of conductance- Experimental set-up and various titrations (strong and weak acid/base)
UNIT V CHROMATOGRAPHIC METHODS 9
Classification of chromatographic methods- Column- Thin layer paper- Gas- High performance liquid Chromatographical methods (principle, mode of separation and technique)- Separation of organic compounds by column and thin layer- Mixture of Cu, Co and Ni by Paper- Separation of amino acids by paper-Estimation of organic compounds by GC and, HPLC.
L: 45 T: 15 Total: 60
TEXT BOOKS
1. Willard, H.H., Merritt.I.I., Dean J.A., and Settle, F.A., Instrumental methods of analysis, Sixth edition, CBS publishers, 1986.
2. Parikh V.M. Absorption spectroscopy of organic molecules Addisen -Wesley Publishing Company, 1994.
REFERENCES
1. Skoog D.A. and Weswt D.MM., Fundamentals of Analytical Chemistry, Saunders -college
Publishing, 1982.
2. Banwell, G.C., Fundamentals of molecular spectroscopy TMH, 1992.
FLUID MECHANICS LABORATORY
LT P 0 0 3
1. Calibration of constant and variable Head meters
2. Calibration of Weirs & Notches
3. Drag reduction studies
4. Flow through straight pipe
5. Flow through Vertical concentric pipe
6. Pressure drop studies in packed column
7. Fluidization
8. Bernoulli's Theorem Apparatus
9. Flow through helical coil and spiral
10. Characteristic curves of centrifugal pump
11. Reynolds's Apparatus
12. Flow of air thro' orifice using Air compressor
Total: 45
MECHANICAL OPERATIONS LABORATORY
LT P 0 0 3
1. Jaw crusher
2. Crushing rolls
3. Ball mill
4. Size analysis by sieving
5. Angle of repose
6. Filter press
7. Leaf filter
8. Cyclone separator
9. Sedimentation
10. Elutriator
11. Rotary Drum filter
12. Effectiveness of screens
Total: 45
COMMUNICATION AND SOFT SKILLS LABORATORY
LT P 0 0 3
(Common to All Branches of III Year B.E./ B.Tech students of Anna University Tiruchirappalli and affiliated colleges)
The aim of the course is two-fold: to enable the students to develop communication skills in the language laboratory and to arrange discussions for developing soft skills in the lab and/or the classroom. Each lab session shall last for three periods.
List of activities that are to be carried out: (15 sessions x 3 periods = 45)
Lab session # 1: Listening and speaking practice exercises with communicative functions. Learning material: the ACD of Spoken English: A Foundation Course for Speakers of Indian Languages (Orient Longman, 2008)
Lab session # 2: Practice with more advanced communicative functions. Learning material: the ACD of Spoken English: A Foundation Course for Speakers of Indian Languages (Orient Longman, 2008)
Lab session # 3: Pronunciation exercises with Oxford Advanced Learners' Dictionary of Current English or any other standard Dictionary
Lab session # 4: Making an oral presentation in English. Learning Material: Professional Presentations VCD (Cambridge University Press)
Lab session # 5: Listening to telephone conversations in English and completing the tasks. Learning material: Essential Telephoning in English ACD (Cambridge University Press)
Lab session # 6: Giving an exposure to and practice with model group discussion and interviews. Learning material: How to Prepare for Group Discussion and Interview Audio Cassette (McGraw-Hill)
Lab session # 7: Giving insights into the format and the task types in the IELTS (International English Language Testing System). Learning Material: Objective IELTS, Intermediate Level (CUP)
Lab session # 8: Understanding the format and the task types in the TOEFL (Test of English as a Foreign Language). Learning Material: Understanding the TOEFL (Educational Testing Services, Princeton)
Lab session # 9: Administering the BEC (Business English Certificate) Diagnostic Test. Learning Material: BEC Practice Materials (British Council, Chennai)
Lab session # 10: Completing the steps involved in Career, Life Planning and Change Management. Learning Material: Developing Soft Skills (Pearson Education)
Lab session # 11: Setting goals and objectives exercises. Learning Material: Developing Soft Skills (Pearson Education)
Lab session # 12: Prioritizing and time planning exercises. Learning Material: Managing Time Multimedia Program CD
Lab session # 13: Taking a Personality Typing/ Psychometric Test Learning Material: 200 Psychometric Test prepared by the CUIC, Anna University Chennai
Lab session # 14: Critical and creative thinking exercises.
Lab session # 15: Improving body language and cross-cultural communication with pictures. Learning material: Body Language (S. Chand and Co.) For a detailed plan, refer to the topics given below;
UNIT I LISTENING AND SPEAKING PRACTICE IN COMMUNICATIVE
FUNCTIONS
Introductions and meetings - Talking about studies and/ or job - Expressing likes and dislikes -Describing daily routines and current activities - Talking about past states and events - Talking about future plans and intentions - Expressing preferences - Giving reasons - Expressing opinions, agreement and disagreement - Seeking and giving advice - Making suggestions
UNIT II SPEAKING APPLICATIONS
Making an oral presentation - Preparing the presentation - Performing the presentation - Beginning -Language - Visual aids and body language - Voice - Ending - Questions - Telephone conversations -Group Discussion and Interview
UNIT III UNDERSTANDING AND PREPARING FOR INTERNATIONAL ENGLISH LANGUAGE EXAMINATIONS
Graded Examinations in Spoken English (GESE) - Spoken English for Work (SEW) - International English Language Testing System (IELTS) - Test of English as a Foreign Language (TOEFL) -Business English Certificate (BEC)
UNIT IV SOFT SKILLS (1)
Preparing for and dealing with change - Motivation, goal-setting and self-esteem - Managing time and stress - Career and life planning - Team work - Leadership traits
UNIT V SOFT SKILLS (2)
Multiple Intelligences - Learning Styles and Personality typing - Critical and creative thinking -People, cultures and self - Intercultural Communication
RESOURCES
1. Kamalesh Sadanand and Susheela Punitha, "Spoken English: A Foundation Course" for Speakers of Indian Languages, Part 2 Audio CD, Hyderabad: Orient Longman, 2008
2. Malcome Goodale, "Professional Presentations", (VCD) New Delhi: Cambridge University
Press, 2005
3. Barbara Garside and Tony Garside, Essential Telephoning in English (Audio CD), Cambridge: Cambridge University Press, 2002
4. Hari Mohan Prasad and Rajnish Mohan, How to Prepare for Group Discussion and Interview (Audio Cassette) Tata McGraw-Hill Publishing
5. Graded Examinations in Spoken English and Spoken English for Work downloadable materials from Trinity College, London
6. International English Language Testing System Practice Tests, CUP
7. Business English Certificate Materials, Cambridge University Press
8. Personality Development (CD-ROM), Times Multimedia, Mumbai
9. Interactive Multimedia Programs on Managing Time and Stress
10. Robert M. Sherfield and et al "Developing Soft Skills" 4th edition, New Delhi: Pearson Education,
2009
Total: 45